Phone Number: (905) 688-5550 ext. 3402 Office: MC E205 Email Address: jmiller@chemiris.labs.brocku.ca
Organometallic mass spectrometry. Fast Atom Bombardment (FAB) mass spectrometry applied to inorganic and bioinorganic problems. NMR studies. Supported catalysts. Sol-gel synthesis of aluminosilicate supports. MS, NMR & FT-IR spectroscopic studies.
Analytical Mass Spectrometry, GC/mass spec , LC/mass spec, and NMR.
Study of supported reagents and strong hydrogen bonds between fluoride ions and materials capable of accepting electron density, involving use of NMR and IR spectra, FAB MS, etc. The organic synthetic utility of the strong hydrogen bond is also being studied.
J.Miller, "Flourine-19 magic-angle spinning NMR", Journal of Progress in Nuclear Magnetic Spectroscopy, (1996).
M. Saraswathi, J.M. Miller and Tim R.B. Jones, "The Negative Ion FABMSof Tris(perfluorophenyl)phosphine", Can. J. Chem. 73 1321 (1995).
L-Z. Chen and J.M. Miller, "Relative Metal-Ion Aff inities of Alkylamines in the Gas-Phase", Journal of Organometallic Chemistry, 448, 225-232 (1993).
L-Z. Chen, J.M. Miller, "Ion-Molecule Reaction of Alkylnitriles and Transition Metal Ions in the Gas-Phase: A Study on Fragmentation Mechanisms of the Adducts", J. Amer. Soc. Mass Spectrom., 2, 120-24 (1991).
F.M. Asseid, C.V.A. Duke and J.M. Miller, "MAS NMR and IR Analysis of the Adsorption of Alkali Metal Fluorides onto Montmorillonite Clay", Can. J. Chem., 68, 1420-24 (1990).
J.M. Miller, "Fast Atom Bombardment Mass Spectrometry of Organometallic, Coordination and Related Compounds", Mass Spectrometry Reviews, 9, 319-347 (1989).