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CHEMISTRY 2P32
Winter 2002
Approximate Lecture Schedule
Chapter References are to Wulfsberg, Principles of Descriptive Inorganic Chemistry
| Lec. # | Date | Topic | Ref. |
| 1 | Jan. 7 | Introduction and Review: Lewis structures, VSEPR, valence bond theory | 1, 7.3 |
| 2 | Jan. 19 | The transition metals: an overview | |
| 3 | Jan. 11 | Introduction to metal complexes | 7.1 |
| 4 | Jan. 14 | Ligands and nomenclature | 7.4, 7.6 |
| 5 | Jan. 16 | Chelating ligands and the chelate effect | 7.5 |
| 6 | Jan. 18 | Structural isomers of transition metal complexes | |
| 7 | Jan. 21 | Stereoisomers: octahedral, tetrahedral, and square planar complexes | |
| 8 | Jan. 23 | What should a bonding theory explain? | |
| 9 | Jan. 25 | Crystal field theory for octahedral complexes | |
| 10 | Jan. 28 | Magnetism and colours of transition metal complexes | |
| 11 | Jan. 30 | Crystal field theory for square and tetrahedral complexes | |
| 12 | Feb. 1 | Consequences of CFSE: Variations in reactivity; Preferred geometries | |
| 13 | Feb. 4 | Hydration and hydrolysis of cations | 2.1-2.3 |
| 14 | Feb. 6 | Predicting hydrolysis of cations; special cases | 2.3-2.5 |
| 15 | Feb. 8 | Oxo anions | 2.6-2.9 |
| Feb. 9 | 10:00 a.m. - 12:00 p.m. Test 1. (Through Feb.1) ROOM: TH 245 | ||
| 16 | Feb. 11 | Strengths of oxo acids. Most common forms of the elements in water. | 2.11-2.12 |
| 17 | Feb. 13 | Solubility rules for salts | 3.1-3.2 |
| 18 | Feb. 15 | Entropy and precipitation: structures of hydrated ions and liquid water | 3.3-3.4 |
| Reading Week Feb. 18 - Feb. 22 | |||
| 19 | Feb. 25 | Enthalpy and precipitation; lattice energies | 3.5-3.6 |
| 20 | Feb. 27 | Lattice types and stabilities | 3.7-3.9 |
| 21 | Mar. 1 | Oxides and their properties | 4.1-4.3 |
| 22 | Mar. 4 | Periodic trends in oxide properties | 4.4-4.5 |
| 23 | Mar. 6 | Silicates, aluminosilicates, and glass | 4.6-4.7 |
| 24 | Mar. 8 | Other polynuclear oxo anions | 4.8-4.9 |
| 25 | Mar. 11 | Oxidation-reduction reactions. Electrochemical cells | 5.1 |
| 26 | Mar. 13 | Dependence of cell potential on concentration: the Nernst equation | 5.2 |
| 27 | Mar. 15 | Speciation of an element as a function of pH and E: Pourbaix diagrams | 5.3 |
| Mar. 16 | 10:00 a.m. - 12:00 p.m. Test 2. (Through March 9) ROOM: TH 245 | ||
| 28 | Mar. 18 | Activity series for metals; redox chemistry of nonmetals | 5.4-5.5 |
| 29 | Mar. 20 | Explosives; extraction of elements from their ores | 5.6-5.7 |
| 30 | Mar. 22 | Physical states and properties of the elements | 6.1-6.3 |
| 31 | Mar. 25 | Periodicity of radii and bond energies | 6.4-6.5 |
| 32 | Mar. 27 | Metals and nonmetals | 6.6-6.7 |
| 33 | Apr. 1 | The Born-Haber cycle for formation of ionic compounds | 6.8 |
| 34 | Apr. 3 | Hard and soft Lewis acids and bases | 8.1-8.2 |
| 35 | Apr. 5 | Applications of HSAB to Geochemistry | 8.9 |
| 36 | Apr. 8 | Applications of HSAB to Coordination Chemistry | 8.10 |
| This page is: http://chemiris.labs.brocku.ca/~chemweb/courses/chem232/lecture.html
Last revised: January 10,2002 by M. F. Richardson © Brock University, 2000 Disclaimer |
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